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News About Acyl

20-September-2008 09:55:58 - Acyl An acyl group An acyl group IUPAC name: alkanoyl is a functional group derived by the removal of one or more hydroxyl group from an oxoacid.1. In organic chemistry, the acyl group is usually derived from a carboxylic acid of the form RC O OH. It therefore has the formula RC=O-, with a double bond between the carbon and oxygen atoms i.e. a carbonyl group, and a single bond between R and the carbon. Acyl groups can also be derived from other types of acids such as sulfonic acids, phosphonic acids, and some others. Acyl halides can be used in Friedel-Crafts acylation to introduce the acyl moiety in an aromatic compound. In biochemistry, acyl CoAs are derivates of fatty acid metabolism, with acetyl CoA as an example. They are actually thiol esters. Contents 1 Examples 2 Acyl species 3 References 4 See also Examples The names of acyl groups are typically derived from the corresponding acid by substituting the acid ending -ic with the ending -yl as shown in the table below. Note that methyl, ethyl, propyl, butyl etc. end in -yl are not acyl but alkyl groups, derived from alkanes. Acyl group name R-CO- Corresponding carboxylic acid name R-CO-OH common systematic common systematic formyl methanoyl formic acid methanoic acid acetyl ethanoyl acetic acid ethanoic acid propionyl propanoyl propionic acid propanoic acid benzoyl benzoic acid acryl propenoyl acrylic acid propenoic acid Acyl species In acyloxy groups the acyl group is bonded to oxygen: R-C=O-O-R' where R-C=O is the acyl group. Acylium ions are cations of the type R-C+=O and play an important role as intermediates in organic reactions 1 for example the Hayashi rearrangement. References ^ a b Compendium of Chemical Terminology, acyl groups See also Acylation Retrieved from http://en..org/wiki/Acyl Categories: Functional groups Views Article Discussion this page History Personal tools Log in / create account Navigation Main page Contents Featured content Current events Random article Search Go Search Interaction Community portal Recent changes Contact Donate to Help Toolbox What links here Related changes Upload file Special pages Printable version Permanent link Cite this page Languages БългарÑ?ки Català Deutsch Español Français Bahasa Indonesia Italiano Polski Português Svenska Tiếng Việt Türkçe 中文 This page was last modified on 17 May 2008, at 16:28

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