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News About Fremys_salt

16-September-2008 16:20:32 - Fremy's salt Fremy's salt IUPAC name Potassium nitrosodisulfonate Identifiers CAS number 14293-70-0 Potassium salt PubChem Potassium salt 24853200 Potassium salt Properties Molecular formula KSO32NO Potassium salt Molar mass 268.33 g/mol Potassium salt Hazards Main hazards Harmful Xn R-phrases R14 R20/21/22 S-phrases S36 Except where noted otherwise, data are given for materials in their standard state at 25 °C, 100 kPa Infobox references Fremy's salt, discovered in 1845 by Edmond Fremy 1814 - 1894, is a chemical compound and a strong oxidizing agent. The formal name is disodium nitrosodisulfonic acid or NOSO3Na2 but Fremy's salt refers equally well to the potassium salt potassium nitrosodisulfonate. Properties and reactions The nitroso compound is a persistent organic radical like TEMPO. It is especially useful in oxidations of phenols to hydroquinones in the Teuber reaction. Preparation The salt can be prepared from sodium nitrite, sodium bicarbonate and sulfur dioxide to disodium hydroxylaminedisulfonate and carbon dioxide followed by one-electron oxidation by electrolysis in a basic solution. References H.-J. Teuber and S. Benz, Chem. Ber., 100, 2918, 1967. This inorganic compound-related article is a stub. Retrieved from http://en..org/wiki/Fremy%27s_salt Categories: Reagents for organic chemistry | Inorganic compound stubsHidden category: Chemical pages needing a structure drawing Views Article Discussion this page History Personal tools Log in / create account Navigation Main page Contents Featured content Current events Random article Search Go Search Interaction Community portal Recent changes Contact Donate to Help Toolbox What links here Related changes Upload file Special pages Printable version Permanent link Cite this page Languages Deutsch Polski This page was last modified on 9 April 2008, at 12:24

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