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14-September-2008 18:38:37 - Activating group In organic chemistry, a functional group is called an activating group if a benzene molecule to which it is attached more readily participates in electrophilic substitution reactions. Benzene itself will normally undergo substitutions by electrophiles, but additional substituents can alter the reaction rate or products by electronically or sterically affecting the interaction of the two reactants. Functional groups are typically divided into three levels of activating ability. Deactivating groups are assigned to similar groupings. Strongly Activating Groups -NH2 -NHR -NR2 -OH -O- Strongly activating substituents favor electrophilic substitution about the ortho and para positions. This is illustrated by drawing the resonance structure's of aniline: 1 Moderately Activating Groups -NHCOCH3 -NHCOR -OCH3 -OR Weakly Activating Groups -CH3 -C2H5 -R -C6H5 Retrieved from http://en..org/wiki/Activating_group Categories: Functional groups Views Article Discussion this page History Personal tools Log in / create account Navigation Main page Contents Featured content Current events Random article Search Go Search Interaction Community portal Recent changes Contact Donate to Help Toolbox What links here Related changes Upload file Special pages Printable version Permanent link Cite this page Languages 中文 This page was last modified on 20 May 2008, at 21:17
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