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14-September-2008 18:38:38 - Alliin Alliin Alliin skeletal view Alliin ball view IUPAC name 2R-2-amino-3-S-prop-2- enylsulfinylpropanoic acid Other names 3-2-Propenylsulfinylalanine S-3-2-Propenylsulfinyl-L-alanine 3-S-Allylsulfinyl-L-alanine S-Allyl-L-cysteine sulfoxide Identifiers CAS number 556-27-4 SMILES C=CCS=OCCC=OON Properties Molecular formula C6H11NO3S Molar mass 177.22 g/mol Appearance White to off white crystalline powder Melting point 163-165 °C 325.4-329 °F Solubility in water Soluble Hazards MSDS External MSDS NFPA 704 1 1 0 Except where noted otherwise, data are given for materials in their standard state at 25 °C, 100 kPa Infobox references Alliin al'-ee-in is a sulfoxide that is a natural constituent of fresh garlic.1 It is a derivative of the amino acid cysteine. When fresh garlic is chopped or crushed, the enzyme alliinase converts alliin into allicin which is primarily responsible for the aroma of fresh garlic. Garlic has been used since antiquity as a therapeutic remedy for oxygen toxicity, and when this was investigated, garlic did indeed show strong antioxidant and hydroxyl radical scavenging properties, possibly owing to the alliin contained within.2 When the effect of alliin is observed on blood cells in vitro, a noted increase in the engulfing capacity of phagocyting cells is seen.3 References ^ Iberl, B et al 1990. Quantitative Determination of Allicin and Alliin from Garlic by HPLC. Planta Med 56: 320-326. doi:10.1055/s-2006-960969. ^ Kourounakis, PN; Rekka, EA Nov. 1991. Effect on active oxygen species of alliin and Allium sativum garlic powder. Res Commun Chem Pathol Pharmacol. 74 2: 249-252. PMID 1667340. ^ Salman, H et al Sep. 1999. Effect of a garlic derivative alliin on peripheral blood cell immune responses. Int J Immunopharmacol. 21 9: 589-597. doi:10.1016/S0192-05619900038-7. PMID 10501628. This article about an amine is a stub. Retrieved from http://en..org/wiki/Alliin Categories: Sulfur amino acids | Nutrition | Amine stubs Views Article Discussion this page History Personal tools Log in / create account Navigation Main page Contents Featured content Current events Random article Search Go Search Interaction Community portal Recent changes Contact Donate to Help Toolbox What links here Related changes Upload file Special pages Printable version Permanent link Cite this page Languages Deutsch Español Bahasa Indonesia Italiano 日本語 Polski This page was last modified on 31 May 2008, at 18:30
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