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20-September-2008 09:29:05 - Insecticide For the Nintendo DS and PC video game, see Insecticide video game. Ovicide redirects here. For other uses, see infanticide zoology. An insecticide is a pesticide used against insects in all developmental forms. They include ovicides and larvicides used against the eggs and larvae of insects respectively. Insecticides are used in agriculture, medicine, industry and the household. The use of insecticides is believed to be one of the major factors behind the increase in agricultural productivity in the 20th century. Nearly all insecticides have the potential to significantly alter ecosystems; many are toxic to humans; and others are concentrated in the food chain. It is necessary to balance agricultural needs with environmental and health issues when using insecticides. Contents 1 Classes of agricultural insecticides 1.1 Organochlorides 1.2 Organophosphates 1.3 Pyrethroids 1.4 Neonicotinoids 1.5 Biological insecticides 2 Environmental effects 2.1 Effects on nontarget species 2.2 DDT 2.3 Pollinator decline 3 Application methods for household insecticides 4 Individual insecticides 4.1 Chlorinated hydrocarbons 4.2 Organophosphorus 4.3 Carbamates 4.4 Phenothiazine 4.5 Pyrethroids 4.6 Neonicotinoids 4.7 Plant derived 5 See also 6 References 7 External links Classes of agricultural insecticides The classification of insecticides is done in several different ways: Systemic insecticides are incorporated by treated plants. Insects ingest the insecticide while feeding on the plants. Contact insecticides are toxic to insects brought into direct contact. Efficacy is often related to the quality of pesticide application, with small droplets such as aerosols often improving performance. Natural insecticides, such as nicotine and pyrethrum, are made by plants as defences against insects. Nicotine based insecticides have been barred in the U.S. since 2001 to prevent residues from contaminating foods. 1 Inorganic insecticides are manufactured with metals and include arsenates copper- and fluorine compounds, which are now seldom used, and sulfur, which is commonly used. Organic insecticides are synthetic chemicals which comprise the largest numbers of pesticides available for use today. Mode of action -- how the pesticide kills or inactivates a pest -- is another way of classifying insecticides. Mode of action is important in predicting whether an insecticide will be toxic to unrelated species such as fish, birds and mammals. Heavy metals, e.g. lead, mercury, arsenic, as well as plant toxins such as nicotine have been used for many years. Various plants have been used as folk insecticides for centuries, including tobacco and pyrethrum. Some farmers are reporting successfully using spray of crudely fermented alcohol as an effective insecticide. Organochlorides With the rise of the modern chemical industry it was possible to form organochlorides, such as chlorinated hydrocarbons. The organochlorides used in chemical warfare tend to be more potent electrophiles than those used as insecticides. For instance mustard gas sulfur mustard, HD is a potent alkylating agent which uses neighbouring group participation of the sulfur to make the alkyl chloride a stronger electrophile. It is likely that the chlorine in DDT is used to tune the lipophilicity of the compound, and to alter the shape and electrostatic effects involved in the interactions of the insecticide and the biomolecules in the target organism. For instance DDT works by opening the sodium channels in the nerve cells of the insect. Organophosphates The next large class developed was the organophosphates, which bind to acetylcholinesterase and other cholinesterases. This results in disruption of nervous impulses, killing the insect or interfering with its ability to carry on normal functions. Organophosphate insecticides and chemical warfare nerve agents such as sarin, tabun, soman and VX work in the same way. Organophosphates have an additive toxic effect to wildlife, so multiple exposures to the chemicals amplifies the toxicity.1 Carbamate insecticides have similar toxic mechanisms but have a much shorter duration of action and are thus somewhat less toxic. Pyrethroids To mimic the insecticidal activity of the natural compound pyrethrum another class of pesticides, pyrethroid pesticides, have been developed. These are nonpersistent and much less acutely toxic than organophosphates and carbamates. Neonicotinoids Synthetic analogues of the natural insecticide nicotine with a much lower acute mammalian toxicity and greater field persistence. Broad-spectrum - systemic insecticides with a rapid action minutes-hours. They are applied as sprays, drenches, seed and soil treatments - often as substitutes for organophosphates and carbamates. Treated insects exibit leg tremors, rapid wing motion, stylet withdrawal aphids, disorientated movement, paralysis and death. Biological insecticides Recent efforts to reduce broad spectrum toxins added to the environment have brought biological insecticides back into vogue. An example is the development and increase in use of Bacillus thuringiensis, a bacterial disease of Lepidopterans and some other insects. It is used as a larvicide against a wide variety of caterpillars. Because it has little effect on other organisms, it is considered more environmentally friendly than synthetic pesticides. The toxin from Bacillus thuringiensis Bt toxin has been incorporated directly into plants through the use of genetic engineering. Other biological insecticides include products based on entomopathogenic fungi e.g. Metarhizium anisopliae, nematodes e.g. Steinernema feltiae and viruses e.g. Cydia pomonella granulovirus. Environmental effects Effects on nontarget species Some insecticides kill or harm other creatures in addition to those they are intended to kill. For example, birds may be poisoned when they eat food that was recently sprayed with insecticides or when they mistake insecticide granules on the ground for food and eat it.1 Sprayed insecticides may drift from the area to which it is applied and into wildlife areas, especially when it is sprayed aerially.1 DDT Main article: DDT One of the bigger drivers in the development of new insecticides has been the desire to replace toxic and irksome insecticides. DDT was introduced as a safer alternative to the lead and arsenic compounds. It is the case that when used under the correct conditions that almost any chemical substance is 'safe', but when used under the wrong conditions most insecticides can be a threat to health and/or the environment. Some insecticides have been banned due to the fact that they are persistent toxins which have adverse effects on animals and/or humans. An oft-quoted case is that of DDT, an example of a widely used and maybe misused pesticide, which was brought to public attention by Rachel Carson's book, Silent Spring. One of the better known impacts of DDT is to reduce the thickness of the egg shells on predatory birds. The shells sometimes become too thin to be viable, causing reductions in bird populations. This occurs with DDT and a number of related compounds due to the process of bioaccumulation, wherein the chemical, due to its stability and fat solubility, accumulates in organisms' fatty tissues. Also, DDT may biomagnify which causes progressively higher concentrations in the body fat of animals farther up the food chain. The near-worldwide ban on agricultural use of DDT and related chemicals has allowed some of these birds--such as the peregrine falcon--to recover in recent years. A number of the organochlorine pesticides have been banned from most uses worldwide and globally they are controlled via the Stockholm Convention on persistent organic pollutants. These include: aldrin, chlordane, DDT, dieldrin, endrin, heptachlor, mirex and toxaphene. Pollinator decline Insecticides can kill bees and may be a cause of pollinator decline, the loss of species that pollinate plants, including through the mechanism of Colony Collapse Disorder,2 in which worker bees from a beehive or Western honey bee colony abruptly disappear. Loss of pollinators will mean a reduction in crop yields.2 Application methods for household insecticides Integrated pest management or IPM in the home begins with restricting the availability to insects of three vital commodities: shelter, water and food. If insects become a problem despite such measures, IPM seeks to control them using the safest possible methods, targeting the approach to the particular pest. Insect repellent, referred to as bug spray, comes in a plastic bottle or aerosol can. Applied to clothing, arms, legs, and other extremities, the use of these products will tend to ward off nearby insects. This is not an insecticide. Insecticide used for killing pests-most often insects, and arachnids-primarily comes in an aerosol can, and is sprayed into the air or a nest as a means of killing the animal. Fly sprays will kill house flies, blowflies, ants, cockroaches and other insects and also spiders. Other preparations are granules or liquids that are formulated with bait that is eaten by insects. For many household pests bait traps are available that contain the pesticide and either pheromone or food baits. Crack and crevice sprays are applied into and around openings in houses such as baseboards and plumbing. Pesticides to control termites are often injected into and around the foundations of homes. Active ingredients of many household insecticides include permethrin and tetramethrin, which act on the nervous system of insects and arachnids. Bug sprays should be used in well ventilated areas only, as the chemicals contained in the aerosol and most insecticides can be harmful or deadly to humans and pets. All insecticide products including solids, baits and bait traps should be applied such that they are out of reach of wildlife, pets and children. Individual insecticides Chlorinated hydrocarbons See also: Category:Organochloride insecticides Aldrin Chlordane Chlordecone DDT Dieldrin Endosulfan Endrin Heptachlor Hexachlorobenzene Lindane gamma-Hexachlorocyclohexane Methoxychlor Mirex Pentachlorophenol TDE Organophosphorus Acephate Azinphos-methyl Bensulide Chlorethoxyfos Chlorpyrifos Chlorpyriphos-methyl Diazinon Dichlorvos DDVP Dicrotophos Dimethoate Disulfoton Ethoprop Fenamiphos Fenitrothion Fenthion Fosthiazate Malathion Methamidophos Methidathion Mevinphos Naled Omethoate Oxydemeton-methyl Parathion Parathion-methyl Phorate Phosalone Phosmet Phostebupirim Phoxim Pirimiphos-methyl Profenofos Philayosfon Terbufos Tetrachlorvinphos Tribufos Trichlorfon Carbamates Aldicarb Carbofuran Carbaryl Methomyl 2-1-Methylpropylphenyl methylcarbamate Phenothiazine Pyrethroids Allethrin Bifenthrin Cypermethrin Deltamethrin Lambda-cyhalothrin Permethrin Resmethrin Tetramethrin Tralomethrin Transfluthrin Neonicotinoids Acetamiprid Clothianidin Imidacloprid Nitenpyram Nithiazine Thiacloprid Thiamethoxam Plant derived Caffeine Derris rotenone Anabasine Anethole mosquito larvae3 Annonin Asimina Pawpaw tree seeds for lice Azadirachtin Carapa Cinnamon leaf oil very effective for killing mosquito larvae3 Cinnamaldehyde very effective for killing mosquito larvae4 Cinnamyl acetate kills mosquito larvae3 Deguelin Derris Desmodium caudatum leaves and roots Eugenol mosquito larvae3 Linalool Myristicin Neem Azadirachtin Nicotiana rustica Nicotine Peganum harmala, seeds smoke from, root Oregano oil kills beetles Rhizoppertha dominica5 bug found in stored cereal Polyketide Pyrethrum Quassia South American plant genus Tetranortriterpenoid Thymol controls varroa mites in bee colonies6 See also Endangered arthropod Pesticide application References ^ a b c Palmer, WE, Bromley, PT, and Brandenburg, RL. Wildlife pesticides - Peanuts. North Carolina Cooperative Extension Service. Retrieved on 2007-10-14. ^ a b Wells M March 11, 2007. Vanishing bees threaten US crops in English, www.bbc.co.uk, BBC News. Retrieved on 2007-09-19. ^ a b c d Cinnamon Oil Kills Mosquitoes. www.sciencedaily.com. Retrieved on 2008-08-05. ^ Cornelia Dick-Pfaff: Wohlriechender Mückentod, 19.07.2004 ^ Oregano Oil Works As Well As Synthetic Insecticides To Tackle Common Beetle Pest. www.sciencedaily.com. Retrieved on 2008-05-23. ^ Almond farmers seek healthy bees External links International Pesticide Application Research Centre IPARC Pestworld.org - Official site of the National Pest Management Association Look up insecticide in Wiktionary, the free dictionary. Classification of insecticides Streaming online video about efforts to reduce insecticide use in rice in Bangladesh. on Windows Media Player, on Real Player How Insecticides Work - Has a thorough explanation on how insecticides work. University of California Integrated pest management program Retrieved from http://en..org/wiki/Insecticide Categories: Insecticides | Pesticides Views Article Discussion this page History Personal tools Log in / create account Navigation Main page Contents Featured content Current events Random article Search Go Search Interaction Community portal Recent changes Contact Donate to Help Toolbox What links here Related changes Upload file Special pages Printable version Permanent link Cite this page Languages العربية Català Česky Dansk Deutsch Eesti Español Français Lietuvių Nederlands 日本語 ‪Norsk bokmÃ¥l‬ Polski Português РуÑ?Ñ?кий Simple English СрпÑ?ки / Srpski Suomi தமிழà¯? Tiếng Việt УкраїнÑ?ька ä¸æ–‡ This page was last modified on 12 August 2008, at 07:26
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